Product ID:SILVALOY 35, AG-CU-ZN-CD
MSDS Date:11/13/1997
FSC:3439
NIIN:00N069383
MSDS Number: CHTCJ

ENGELHARD CORP

235 KILVERT ST
WARWICK, RI 02886
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 401-739-9550

Cage: ENGEL

ENGELHARD CORP

SOLON, OH 44139 US

Telephone: 216-292-9200

Cage: ENGEL

SILVER (SARA 313) (CERCLA)

CAS: 7440-22-4

RTECS: VW3500000

Fraction By Weight: 19-60%

OSHA PEL 0.01 MG/M3

ACGIH TLV: 0.1 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

COPPER (SARA 313) (CERCLA)

CAS: 7440-50-8

RTECS: GL5325000

Fraction By Weight: 5-50%

OSHA PEL 0.1MG/M3 FUME/1 DUST

ACGIH TLV: 0.2 MG/M3 FUME

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

(ORAL,RAT) 225 MG/KG

CAS: 7440-43-9

RTECS: EU9800000

Fraction By Weight: 1-30%

OSHA PEL 0.2 MG/M3 DUST; Z-2

ACGIH TLV: 0.01 MG/M3 DUST

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ZINC (SARA 313) (CERCLA)

CAS: 7440-66-6

RTECS: ZG8600000

Fraction By Weight: 5-40%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

HLTH EFTS DESCRIBED ABOVE ONLY APPLY IF DUST/FUME

RTECS: 9999999ZZ

POISONING, RSLTG IN HEMOLYTIC ANEMIA & LIVER, KIDNEY

RTECS: 9999999ZZ

AT RELATIVELY LOW CONCS, MAY RSLT IN KIDNEY DMG & AN

RTECS: 9999999ZZ

BEEN ASSOC W/COPPER DEFICIENCY ANEMIA. PRLNGD/EXCESS

RTECS: 9999999ZZ

DISCOLORATION OF EYES, SKIN/MUCOUS MEMBRANES.

RTECS: 9999999ZZ

PLAN (SPCC). SUCH PLAN SHOULD INCL PROC APPLIC

RTECS: 9999999ZZ

DISP AS APPROP. **NOTE** IN EVENT OF ACCIDENTAL

RTECS: 9999999ZZ

ADDITIONALLY, PROPER EXPOS CTLS & PERSON PROT EQUIP

RTECS: 9999999ZZ

(SEE DISPOSAL CONSIDERATIONS SECTION).

RTECS: 9999999ZZ

RECLAMATION REQUIREMENTS WILL VARY BY

RTECS: 9999999ZZ

REGULATORY AUTH. **NOTE** CHEM ADDNS,

RTECS: 9999999ZZ

INFO PRESENTED ABOVE INCOMPLETE,

RTECS: 9999999ZZ

BE DISPOSED/RECYCLED/RECLAIMED I/A/W FEDERAL,

RTECS: 9999999ZZ

(PRACTICES FOR RESPIRATORY PROTECTION).

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 3
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: EYE & SKIN CONT: MAY CAUSE
IRRIT. INHAL: MAY CAUSE RESP TRACT IRRIT, CHEST PAIN & LABORED
BRTHG. SEV EXPOS MAY LEAD TO PULM EDEMA/EXCESS CADMIUM ABSORP RSLTG
IN PULM EMPHYSEMA, AND/OR LIVER & K IDNEY DYSFUNCTION. INGEST: IS
HARMFUL. MAY CAUSE ABDOM PAIN, NAUS, VOMIT & DIARR. COPPER
POISONING CAN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CADMIUM: IARC SUP 7, P 139, 1987:GRP 2A.
NTP 7TH ANN RPT, 1994: ANTIC TO BE CARCIN. OSHA REGULATED, 29 CFR
1910.1027.
Effects of Overexposure:HLTH HAZ: RSLT IN HEMOLYTIC ANEMIA & KIDNEY,
LIVER & SPLEEN DMG. NOTE: INHAL OF FUMES MAY CAUSE FLU-LIKE ILLNESS
CALLED METAL FUME FEVER. TYPICALLY METAL FUME FEVER BEGINS 4-12 HRS
AFTER SUFFICIENT EX POS TO FRESHLY FORMED FUMES. FIRST SYMPS ARE
METALLIC TASTE, DRYNESS & IRRIT OF THROAT. COUGH & SHORTNESS OF
(SUPDAT)
Medical Cond Aggravated by Exposure:MAY ADVERSELY AFFECT EXISTING
MEDICAL CONDITIONS, SUCH AS EYE, SKIN, RESPIRATORY, BLOOD, LIVER
AND/OR KIDNEY AILMENTS. INDIVIDUALS W/WILSON'S DISEASE ARE AT
INCREASED RISK OF COPPER POISONONG.

First Aid:EYE CONT: FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS. IF
IRRIT DEVELOPS, CALL PHYS. SKIN CONT: IMMED WASH W/SOAP & PLENTY OF
WATER. IF IRRIT PERSISTS, CALL PHYS. INHAL: IF EXPOSED TO EXCESS
LEVELS OF METAL FUMES, REMOVE TO FRESH AIR & SEEKMED ATTN. INGEST:
IF CONSCIOUS & ABLE TO SWALLOW, GIVE LG AMTS OF WATER TO DILUTE. IF
VOMIT OCCURS, KEEP HEAD BELOW HIPS TO HELP PVNT ASPIR. GET MED ATTN
IMMED.

Extinguishing Media:USE CARBON DIOXIDE, CHEMICAL FOAM OR DRY CHEMICAL.
USE ANY MEANS FOR EXTINGUISHING SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . DO NOT USE WATER ON METAL FIRES.
Unusual Fire/Explosion Hazard:NOT FIRE/EXPLO HAZ IN SOLID FORM. FINELY
DIVIDIDED DUST MAY IGNITE & BURN RAPIDLY WHEN MIXED W/AIR IN PROPER
PROPORTIONS. TOXIC METAL FUMES MAY BE (SUPDAT)

Spill Release Procedures:CNTN SPILLAGE & SCOOP UP/VACUUM. NOTIFICATION
OF NATL RESPONSE CTR (800/424-8802) MAY BE REQD. REFER TO EPA, DOT
& APPLIC STATE & LOC REGS FOR CURRENT RESPONSE INFO. IT IS REC THAT
EACH USER ESTABLISH SPILL PREVENTION, CTL & COUNTERMEASURE(ING 11)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, DRY LOCATION AWAY FROM
INCOMPATIBLE MATLS. USE ONLY WITH ADEQUATE VENTILATION.
Other Precautions:NOTE: CONSULT MOST RECENT OSHA CADMIUM STD
(1910.1027) & ITS ATTACHMENTS, APPENDICES, ETC, FOR FULL
REQUIREMENTS, SOME OF WHICH ARE NOT COVERED IN THIS MSDS. AVOID
BRTHG OR CONT W/ANY DUST, MIST/FUMES RSLTG FROM USE OF THIS PROD.

Respiratory Protection:IF DUST/FUME IS GENERATED, NIOSH APPRVD RESP MAY
BE NEC. FOLLOW ALL REQUIREMENTS FOR RESP PROGRAMS & SELECTION SET
FORTH IN OSHA REGS (29 CFR 1910.134, REDESIGNATED TO 29 CFR
1910.139 AS OF APRIL 8, 1 998) AND IN ANSI Z88.2-92 (ING 19)
Ventilation:GEN; LOC EXHAUST VENT AS NEC TO CTL ANY AIR CONTAMINANTS TO
W/IN THEIR PELS/TLVS DURING USE OF THIS PRODUCT.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . BODY
PROT AS NEC TO PVNT SKIN CONT. CONT NEHC FOR MORE SPECIFIC INFO.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT EAT,
DRINK, OR SMOKE IN WORK AREA.
Supplemental Safety and Health
SPEC GRAV: 8.71-9.45 (H*2O =1). EXPLO HAZ: RELEASED IN FIRE SITUATION.
MATLS TO AVOID: TURPENTINE, MAGNESIUM METAL, AMMONIUM NITRATE,
HYDROGEN SULFIDE. EFTS OF OVEREXP: BREATH MAY OCCUR ALONG W/HDCH,
FATIG, NAUS, VOMIT, MUSCLE & JOINT PAIN, FEVER & CHILLS. SYNDROME
RUNS ITS COURSE IN 24-48 HRS. NOTE: POTNTL (ING 6)

Melt/Freeze Pt:M.P/F.P Text:1128F,609C
Spec Gravity:SUPDAT
Solubility in Water:INSOLUBLE
Appearance and Odor:METALLIC WIRE, ROD OR STRIP. ODORLESS.

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, & BASES, STRONG OXIDIZERS, ACETYLENE, AMMONIA, HYDROGEN
PEROXIDE, CHLORINE, BROMINE, IODINE, (SUPDAT)
Stability Condition to Avoid:NONE EXPECTED.
Hazardous Decomposition Products:OR BY-PRODS: TOXIC METAL OXIDES ARE
EMITTED WHEN HEATED ABOVE MELTING POINT. AMT OF FUME EVOLVED AS
TEMPERATURE RISES.

Waste Disposal Methods:US EPA WASTE NOS: D006, D011. PROD MAY BE HAZ
WASTE UNDER EPA WASTE REGS. BEFORE DISP, PROD/MIX CNTNG PROD SHOULD
BE TESTED FOR TOX CHARACT (TC) UNDER CURRENT EPA HAZ WAS REGS TCLP
TESTING PROC, 40 CF R PART 261 ET SEQ. DISPOSAL/RECYCLING/ (ING 15)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.